Course Code: 110
Title of the Course: Applied Chemistry

Credits 4

I Water Conditioning
Industrial: Types units of hardness; Softening; (principle, reactions, advantage, limitation Comparison of) Lime-Soda (no methods), Zeolite, de-mineralization process; Numericals on lime-soda and Zeolite process; Boiler Troubles(causes, Effect on boiler operation & methods of prevention) Carry over-priming foaming; Scale sludge, caustic embrittlement, Boiler corrosion; Internal conditioning-(phosphate, carbonate, calgon).
Domestic: coagulation & sterilization using UV, ozone, chlorine, Break point chlorination.

II Corrosion and Battery Science
Introduction, Cause and Consequences of corrosion, Factors influencing corrosion Chemical & electrochemical corrosion. Mechanisms of electrochemical corrosion; Pilling-Bedworth rule; Differential aeration theory of corrosion.
Types of corrosion and Preventive Methods: Pitting; Inter granular, Stress, Waterline Corrosion; Corrosion prevention a) Design & material selection, b) Cathodic & anodic protection, c) protective surface coating- (only principle Methods not required)-tinning, galvanizing & powder coating, metal cladding and electroplating.
Battery: Secondary - Nickel-cadmium. Fuel cell applications, advantages and limitations eg Alkaline Fuel Cell.

III Materials and Green Chemistry
Cement: Portland cement: Raw material, manufacture, process parameters, role of microscopic constituents, Properties:-Setting & hardening; heat of hydration, soundness; Types (characteristics, application) High alumina, White, Rapid hardening, Ready Mix Concrete, flyash (properties, advantage, limitation, application) as cementing material.
Green Chemistry: Introduction, principles, concept of carbon credits.

IV Fuels and Energy
Fuels: Introduction: Calorific value, HCV & LCV; Determination of CV by Bomb & Boy‟s calorimeter; numericals; Solid fuels:- significance of proximate and Ultimate analysis; numericals (Dulongs formula).
Liquid and Gaseous fuels:- bubble tower fractional distillation of crude oil (boiling point wise separation only); Knocking in IC & Compression engine; Octane & Cetane number, Doping agents (Antiknocking, Anti oxidants, antiicing) Fisher-tropsch process of manufacture of synthetic gasoline; catalytic cracking (Only Principal, Definition, reactions and catalysts used, Advantage, Method of fixed bed & fluid bed not required) Bio-diesel, CNG (Composition, properties, advantages, limitations, applications, method of preparation not needed).

V Lubrication and Combustion Calculations
Lubricants: Introduction, mechanism; Hydrodynamic, boundary & extreme pressure lubrication; Classification-solid, semisolid & liquid lubricants; Biodegradable lubricants (properties, application, advantage limitation); Properties of greases:- Drop test & consistency test; Properties of liquid lubricants (definition, significance) flash & fire point, viscosity & viscosity index, Cloud & Pour Point: Criteria for selection of lubricant- IC engine, refrigeration, gear, transformer, steam turbine, delicate mechanical system.
Numericals on Combustion estimations.

Text Books:
1. Text Book of Engineering Chemistry, S. S. Dara, S. Chand and Company Ltd., New Delhi.
2. Textbook of Engineering Chemistry, P. C. Jain and Monica Jain, Dhanpat Rai and Sons, New Delhi.
3. Text Book of Environmental Chemistry and Pollution Control, S. S. Dara; S. Chand and Company Ltd., New Delhi.
4. Textbook of Engineering Chemistry, S. N. Narkhede, R. T. Jadhav, A. B. Bhake, A. U. Zadgaonkar, Das Ganu Prakashan, Nagpur.
5. Applied Chemistry, A. V. Bharati and Walekar, Tech Max Publications, Pune.
6. Engineering Chemistry, Arty Dixit, Dr. Kirtiwardhan Dixit, Harivansh Prakashan, Chandrapur.

Reference Books:
1. A solid slate Chemistry and its Application by Anthony R. West, John Wiley & Sons(1989)
2. A Text book of Engineering Chemistry by Shashi Chawla; Dhanpat Rai & sons, New Delhi
3. A textbook of polymer science Fred. Billmeyer Jr. Wiley India Third edition
4. Applied chemistry by N. krishnamurthy . P.vallinavagam. and k. .Jeysubramanian TMH
5. Applied chemistry for engineers by T.S.Gyngell
6. Chemistry in Engineering by Lloyd A.Munro, Prentice-hall, Inc Nj
7. Chemistry of advanced materials – CNR Rao, Rsc Pbl.
8. Chemistry of Cement, J. D. Lee, Mcgraw Hill Publishing Company, New Delhi.
9. Chemistry of Engineering Materials, by Rober B Leigeou Mc Graw-Hill Book Company, Inc New York
10. Chemistry, Raymond Chang. (Tata McGraw Hill).
11. Corrosion Engineering by Mars G. Fontana and Norbert D. Green Mc Graw Hill Book Co. Tokyo
12. Electrochemistry, Philip H. Rieger (Chapman and Hail)
13. Engineering Chemistry (Vol. I and II ) by Rajaram and Kuriakose.
14. Engineering Chemistry B.K.Sharma Krishna Prakashan media private LTD.
15. Engineering Chemistry by Gyngell, McGraw Hill Publishing Company, New Delhi.
16. Engineering chemistry by R.gopalan, and others, Vikas publications
17. Engineering Chemistry by R.V.Gadag, A.Nityananda Shetty ; I K International Publishing House, New
Delhi
18. Engineering Chemistry, B. S. Sivasankar, Tata Mcgraw Hill Publishing Company, New Delhi.
19. Engineering Chemistry, O. G. Palan, Tata Mcgraw Hill Publishing Company, New Delhi.
20. Engineering Chemistry, R. Shivakumar, Tata Mcgraw Hill Publishing Company, New Delhi.
21. Engineering Chemistry, Saraswat and Thakur, Vikas Publication, New Delhi.
22. Engineering materials. Venneth G Budinski (Prentice-- Hall of India).
23. Environmental chemistry, A. K. De (New Age International Publishers)
24. Fuels and Combustion by Amir Circar, Orient Longmans
25. Fundamentals of corrosion by Michael Henthorne, Chemical Engineering
26. Fundamentals of Engineering Chemistry (theory and Practice), S. K. Singh (New Age International
Publishers)
27. Materials science and engineering an introduction, William D. Callister, (Jr.,Wiley.publisher)
28. Polymer science and technology, Joel R Fried (Prentice -. Hall of India).
29. Polymer Science, V.R. Gowarikar (Wiley Eastern Ltd.).
30. Text book of engineering chemistry, R.N. Goyal and Harrmendra Goel, (Ane books India).
31. Tyre Technology, Tom French, Adam Hilger, New York
32. Water treatment by F.I. Bilane, Mir publisher
33. Water treatment for industrial and other use by Eskel Nordell, Rein hold Publishing Corporation,New York
34. Chemistry, Raymond Chang. (Tata McGraw Hill).
35. Principles of the solid state, H.V. Keer (New age international publishers).