{"id":6506,"date":"2021-10-30T07:41:01","date_gmt":"2021-10-30T07:41:01","guid":{"rendered":"https:\/\/www.goseeko.com\/blog\/?p=5689"},"modified":"2025-12-14T10:49:35","modified_gmt":"2025-12-14T05:19:35","slug":"what-is-a-calomel-electrode","status":"publish","type":"post","link":"https:\/\/www.goseeko.com\/blog\/what-is-a-calomel-electrode\/","title":{"rendered":"What is a Calomel electrode"},"content":{"rendered":"\n<p>A calomel electrode is a type of reference electrode based on reactions between mercury (I) chloride (calomel) and elemental mercury. These electrodes are commonly used in voltmeters and pH meters.<\/p>\n\n\n\n<p>A good non-polarizable calomel electrode is very robust, which is why it is used by many two-electrode systems where the supporting electrolyte is a non-reactive chloride salt.<\/p>\n\n\n\n<p>The structure of the calomel electrode consists of an outer glass tube with a frit on the bottom that enables electrical contact with a solution outside the electrode. An inner tube is placed in an outer tube. The bottom of the inner tube is made of glass. Wool on the bottom to create electrical contact between the contents of both tubes.<\/p>\n\n\n\n<p>The mercury paste is packed in the innermost tube and the mercury chloride is dispersed in a saturated solution of potassium chloride.<\/p>\n\n\n\n<figure class=\"wp-block-image\"><img decoding=\"async\" src=\"https:\/\/lh5.googleusercontent.com\/gSFil-aN2ATMgObV0RbReldjC5YwPCeezwdKcSd0RLu73vpCl6789XS6XRJ1TQ6OnzTCsSPBUBALVGoSNkRljEz_AxKlfA85X8QWXQ9xVGB6GetrWxzBg63DI5kQkmO05P5cC3ja=s0\" alt=\"\"\/><\/figure>\n\n\n\n<p>&nbsp;Diagram of a calomel electrode.<\/p>\n\n\n\n<p>The calomel electrode is a type of half-cell in which the electrode is mercury coated with calomel (Hg2Cl2) and the electrolyte is a solution of potassium chloride and saturated calomel.&nbsp;<\/p>\n\n\n\n<p>Functioning<\/p>\n\n\n\n<p>For the calomel electrode to work, the Hg-Hg 2 Cl 2 pair must react, either gaining or losing electrons.<\/p>\n\n\n\n<h2 class=\"wp-block-heading\"><strong>Cathodic<\/strong><\/h2>\n\n\n\n<p>When the reduction or gain of electrons occurs inside the calomel electrode, we have the following reactions:<\/p>\n\n\n\n<p>Hg 2 Cl 2 \u2192 Hg 2 2+ &nbsp; + 2Cl \u2013&nbsp; (Ionization)<\/p>\n\n\n\n<p>Hg 2 2+ &nbsp; + 2e \u2013 &nbsp; \u2192 2Hg (Reduction)<\/p>\n\n\n\n<p>Hg 2 Cl 2&nbsp; + 2e \u2013 &nbsp; \u2192 2Hg + 2Cl \u2013 (Net reaction)<\/p>\n\n\n\n<p>Therefore, Hg 2 Cl 2 gains electrons reducing to metallic mercury.<\/p>\n\n\n\n<p>The potential E of the electrode when the reduction occurs is given by the equation:<\/p>\n\n\n\n<p>E = E\u00ba \u2013 0.0591 Log [Cl \u2013 ]<\/p>\n\n\n\n<p>Where it is observed that E depends exclusively on the concentration of Cl \u2013 ions , E \u00b0 being the standard reduction potential for this electrode measured against the standard hydrogen electrode.<\/p>\n\n\n\n<h2 class=\"wp-block-heading\"><strong>Anodic<\/strong><\/h2>\n\n\n\n<p>Inside the electrode an oxidation process can also occur:<\/p>\n\n\n\n<p>2Hg \u2192 Hg 2 2+&nbsp; + 2e \u2013 &nbsp; (Oxidation)<\/p>\n\n\n\n<p>Hg 2 2+ &nbsp; + 2Cl \u2013&nbsp; \u2192 Hg 2 Cl 2 &nbsp; &nbsp; (Precipitation)<\/p>\n\n\n\n<p>2Hg + 2Cl \u2013 &nbsp; \u2192 Hg 2 Cl 2 &nbsp; + 2e \u2013 &nbsp; (Net reaction)<\/p>\n\n\n\n<p>That is, the mercury is oxidized to generate more Hg 2 Cl 2 .<\/p>\n\n\n\n<p>The potential E in this case is given by:<\/p>\n\n\n\n<p>E = E\u00ba + 0.0591 Log [Cl \u2013 ]<\/p>\n\n\n\n<p>And again, E depends on [Cl \u2013 ].<\/p>\n\n\n\n<h2 class=\"wp-block-heading\"><strong>General reaction<\/strong><\/h2>\n\n\n\n<p>The general reaction for the calomel electrode is:<\/p>\n\n\n\n<p>Hg 2 Cl 2 (s) + 2e \u2013&nbsp; \u21cc 2Hg (l) + 2Cl \u2013<\/p>\n\n\n\n<p>The sense of balance above will depend on the medium where the electrode is contacted. The Cl \u2013 ion determines the solubility of Hg 2 Cl 2 , which in turn affects the formation or oxidation of Hg.<\/p>\n\n\n\n<p>And the potential determined for a specified concentration of Cl ions \u2013 will be equal to:<\/p>\n\n\n\n<p>E calomel = E red \u2013 E ox<\/p>\n\n\n\n<p>E calomel being the potential <a href=\"https:\/\/dewa4dku.one\/\">dewa4dku <\/a>that is reported as a reference in certain potential tables<\/p>\n\n\n\n<p><strong>Interested in learning about similar topics? Here are a few hand-picked blogs for you!<\/strong><\/p>\n\n\n\n<ol class=\"wp-block-list\">\n<li>What is <a href=\"https:\/\/www.goseeko.com\/blog\/what-is-a-calorimeter\/\">Calorimeter<\/a>?<\/li>\n\n\n\n<li>What is Calorific value?<\/li>\n<\/ol>\n\n\n\n<p><\/p>\n","protected":false},"excerpt":{"rendered":"<p>A calomel electrode is a type of reference electrode based on reactions between mercury (I) chloride (calomel) and elemental mercury.<\/p>\n","protected":false},"author":28,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"_jetpack_memberships_contains_paid_content":false,"footnotes":""},"categories":[1],"tags":[],"class_list":["post-6506","post","type-post","status-publish","format-standard","hentry","category-uncategorized"],"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v25.3.1 - https:\/\/yoast.com\/wordpress\/plugins\/seo\/ -->\n<title>What is a Calomel electrode - Goseeko blog<\/title>\n<meta name=\"robots\" content=\"index, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" \/>\n<link rel=\"canonical\" href=\"https:\/\/www.goseeko.com\/blog\/what-is-a-calomel-electrode\/\" \/>\n<meta property=\"og:locale\" content=\"en_US\" \/>\n<meta property=\"og:type\" content=\"article\" \/>\n<meta property=\"og:title\" content=\"What is a Calomel electrode - Goseeko blog\" \/>\n<meta property=\"og:description\" content=\"A calomel electrode is a type of reference electrode based on reactions between mercury (I) chloride (calomel) and elemental mercury.\" \/>\n<meta property=\"og:url\" content=\"https:\/\/www.goseeko.com\/blog\/what-is-a-calomel-electrode\/\" \/>\n<meta property=\"og:site_name\" content=\"Goseeko blog\" \/>\n<meta property=\"article:publisher\" content=\"https:\/\/www.facebook.com\/goseeko\" \/>\n<meta property=\"article:published_time\" content=\"2021-10-30T07:41:01+00:00\" \/>\n<meta property=\"article:modified_time\" content=\"2025-12-14T05:19:35+00:00\" \/>\n<meta property=\"og:image\" content=\"https:\/\/lh5.googleusercontent.com\/gSFil-aN2ATMgObV0RbReldjC5YwPCeezwdKcSd0RLu73vpCl6789XS6XRJ1TQ6OnzTCsSPBUBALVGoSNkRljEz_AxKlfA85X8QWXQ9xVGB6GetrWxzBg63DI5kQkmO05P5cC3ja=s0\" \/>\n<meta name=\"author\" content=\"Gunjan\" \/>\n<meta name=\"twitter:card\" content=\"summary_large_image\" \/>\n<meta name=\"twitter:creator\" content=\"@goseeko\" \/>\n<meta name=\"twitter:site\" content=\"@goseeko\" \/>\n<meta name=\"twitter:label1\" content=\"Written by\" \/>\n\t<meta name=\"twitter:data1\" content=\"Gunjan\" \/>\n\t<meta name=\"twitter:label2\" content=\"Est. reading time\" \/>\n\t<meta name=\"twitter:data2\" content=\"3 minutes\" \/>\n<script type=\"application\/ld+json\" class=\"yoast-schema-graph\">{\"@context\":\"https:\/\/schema.org\",\"@graph\":[{\"@type\":\"Article\",\"@id\":\"https:\/\/www.goseeko.com\/blog\/what-is-a-calomel-electrode\/#article\",\"isPartOf\":{\"@id\":\"https:\/\/www.goseeko.com\/blog\/what-is-a-calomel-electrode\/\"},\"author\":{\"name\":\"Gunjan\",\"@id\":\"https:\/\/www.goseeko.com\/blog\/#\/schema\/person\/843a7ac71fc4ae8c177dbb7820f2dc9c\"},\"headline\":\"What is a Calomel electrode\",\"datePublished\":\"2021-10-30T07:41:01+00:00\",\"dateModified\":\"2025-12-14T05:19:35+00:00\",\"mainEntityOfPage\":{\"@id\":\"https:\/\/www.goseeko.com\/blog\/what-is-a-calomel-electrode\/\"},\"wordCount\":474,\"commentCount\":0,\"publisher\":{\"@id\":\"https:\/\/www.goseeko.com\/blog\/#organization\"},\"image\":{\"@id\":\"https:\/\/www.goseeko.com\/blog\/what-is-a-calomel-electrode\/#primaryimage\"},\"thumbnailUrl\":\"https:\/\/lh5.googleusercontent.com\/gSFil-aN2ATMgObV0RbReldjC5YwPCeezwdKcSd0RLu73vpCl6789XS6XRJ1TQ6OnzTCsSPBUBALVGoSNkRljEz_AxKlfA85X8QWXQ9xVGB6GetrWxzBg63DI5kQkmO05P5cC3ja=s0\",\"inLanguage\":\"en-US\",\"potentialAction\":[{\"@type\":\"CommentAction\",\"name\":\"Comment\",\"target\":[\"https:\/\/www.goseeko.com\/blog\/what-is-a-calomel-electrode\/#respond\"]}]},{\"@type\":\"WebPage\",\"@id\":\"https:\/\/www.goseeko.com\/blog\/what-is-a-calomel-electrode\/\",\"url\":\"https:\/\/www.goseeko.com\/blog\/what-is-a-calomel-electrode\/\",\"name\":\"What is a Calomel electrode - 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